[ Disc 1 ]

- Director & Producer Commentary (using PIP for Blu-ray) - Audio & Video commentaryCrew Commentary

[ Disc 2 ]

- Deleted Scenes
- The Road to Casino Royale- Documentary
- Ian Fleming's Incredible Creation- Documentary
- James Bond in the Bahamas- Documentary
- Ian Fleming: The Secret Road to Paradise- Documentary
- Death in Venice- Documentary
- Beconing Bond- Documentary
- James Bond: For Real- Documentary
- Bond Girls Are Forever: A New Kind of Woman- Documentary
- Bond Girls Are Forever: Bond Meets His Match- Documentary
- Bond Girls Are Forever: Children of Our Generations- Documentary
- The Art of the Freerun
- Catching a Plane: From Storyboard to Screen- Scene Deconstruction
- Filmmaker Profile: Chris Corbould, Special Effects
- Filmmaker Profile: Phil Meheux, Director of Photography
- Filmmaker Profile: Gary Powell, Stunt Coordinator
- Filmmaker Profile: Alexander Witt, Second Unit Director
- Filmmaker Profile: David Arnold, Composer
- Chris Cornell "You Know My Name"

James Bond goes on his first ever mission as a 00. Le Chiffre is a banker to the world's terrorists. He is participating in a poker game at Montenegro, where he must win back his money, in order to stay safe among the terrorist market. The boss of MI6, known simply as M sends Bond, along with Vesper Lynd to attend this game and prevent Le Chiffre from winning. Bond, using help from Felix Leiter, Mathis and having Vesper pose as his wife, enters the most important poker game in his already dangerous career. But if Bond defeats Le Chiffre, will he and Vesper Lynd remain safe?